Vasantha Lakshmi

 

Arbeitsgebiet

Mo-katalysierte Hydrostannylierungen


Publikationen

Formal total synthesis of (±)-herbertene-1,13-diol and (±)-α-herbertenol via Ireland ester Claisen rearrangement and RCM reaction sequence, A. Srikrishna and B. Vasantha Lakshmi, Synlett, 2005, 1173.

Construction of vicinal quaternary carbon atoms by Ireland ester Claisen rearrangement. Total synthesis of (±)-herbertenolide, (±)-herberteneacetal, (±)-herbertene-1,14-diol and (±)-herbertene-1,15-diol, A. Srikrishna and B. Vasantha Lakshmi, Tetrahedron Lett., 2005, 46, 4879.

The first total synthesis of a bioactive metabolite, a spirobenzofuran isolated from the fungi Acremonium sp. HKI 0230, A. Srikrishna and B. Vasantha Lakshmi, Tetrahedron Lett., 2005, 46, 7029.

The first total synthesis of (±)-lagopodin A, A. Srikrishna, B. Vasantha Lakshmi and P. C. Ravikumar, Tetrahedron Lett., 2006, 47, 1277.

Construction of spiro[5.5]undecanes containing a quaternary carbon atom adjacent to a spirocentre via an Ireland ester Claisen rearrangement and RCM reaction sequence. Total syntheses of (±)-α-chamigrene, (±)-β-chamigrene and (±)-laurencenone C, A. Srikrishna, B. Vasantha Lakshmi and M. Mathews, Tetrahedron Lett., 2006, 47, 2103.

Pyridinium Chlorochromate mediated oxidative cyclisation of sterically crowded γ-δ-unsaturated alcohols, A. Srikrishna, B. Vasantha Lakshmi and A.V.S. Sudhakar, Tetrahedron Lett., 2007, 48, 7610.

B. V. Lakshmi, U. Kazmaier “A straightforward approach towards substituted Morita-Baylis-Hillman (MBH) products via hydrostannation of acetylenic ketones”, Synlett, 2010, 407-410.

B. V. Lakshmi, U. K. Wefelscheid, U. Kazmaier, “Synthesis of Arylstannanes from Silyl Triflates via Aryne Intermediates”, Synlett, 2011, 345–348.